Advanced Energy Technologies
Azin Hasanvand; Mehdi Pourabdoli; Ahmad Ghaderi Hamidi
Abstract
The effect of Al2O3 (1-10 wt %) and Y2O3 (1-10 wt %) additions on thermochemical heat storage properties of Co3O4/CoO system was investigated by thermogravimetry, XRD, and SEM analyses. Results showed that the addition of Al2O3 to Co3O4 at constant 8 h mechanical activation improved the redox cycle stability ...
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The effect of Al2O3 (1-10 wt %) and Y2O3 (1-10 wt %) additions on thermochemical heat storage properties of Co3O4/CoO system was investigated by thermogravimetry, XRD, and SEM analyses. Results showed that the addition of Al2O3 to Co3O4 at constant 8 h mechanical activation improved the redox cycle stability and increased oxygen sorption value and rate. It was found that oxygen sorption and their rate decreased with increasing the alumina content to more than 8 wt %. The formation of the spinel phase and an increase in its amount by increasing the alumina content led to a decrease in the oxygen sorption capacity. SEM studies showed that Al2O3 prevented the sintering and particle growth of cobalt oxide particles during reduction and re-oxidation processes. In addition, results showed that the addition of Y2O3 in all ranges to Co3O4 improved the redox cycle stability of cobalt oxide; however, it significantly decreased the oxygen sorption in the Co3O4/CoO system. XRD patterns of a sample containing 10 wt % yttria before the redox process indicated the presence of only Co3O4 phase; however, after three redox cycles, other phases including CoO and Y2O3 appeared.
Morteza Keshavarz; Behnam Mostajeran Goortani
Abstract
The amine regenerator of acid removal unit in South Pars Gas Complex, Assalouyeh, Iran was modeled. This model was fitted to assess the large scale columns and allow application of solar thermal energy for production of low pressure steam. Heat transfer fluids including Therminol oil, sulfur, or salt ...
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The amine regenerator of acid removal unit in South Pars Gas Complex, Assalouyeh, Iran was modeled. This model was fitted to assess the large scale columns and allow application of solar thermal energy for production of low pressure steam. Heat transfer fluids including Therminol oil, sulfur, or salt melt could be applied to yield thermal energy from a solar collector and to store and transfer it to the reboiler of columns. The Angstrom model was adopted here to simulate solar irradiance. Solar irradiance data for the city of Assalouyeh, during the years of 2009-2014, were collected and applied. The results indicated that based on a reboiler duty of around 21.8 MW, a solar collector area of 148,000 m2 was required with a mass of heat transfer and storage medium of 1247255 kg oil, 1787732 kg salt melt and 3803686 kg sulfur, respectively. This model was applied as an analytical tool to explore and describe the following two problems encountered during real plant operation: fouling in the amine heat exchangers and increasing regenerator pressure.
