Renewable Energy Resources and Technologies
Ayowumi Rita Soji-Adekunle; Betiku Eriola; Abraham A. Asere
Abstract
This study used ternary substrates consisting of honne, neem, and yellow oleander (HONOYO) oil blend to produce methyl-esters for sustainability of raw materials for biodiesel synthesis. A biomass-based catalyst from calcined mixed agro-wastes consisting of kolanut pod, cocoa pod, and plantain peel ash ...
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This study used ternary substrates consisting of honne, neem, and yellow oleander (HONOYO) oil blend to produce methyl-esters for sustainability of raw materials for biodiesel synthesis. A biomass-based catalyst from calcined mixed agro-wastes consisting of kolanut pod, cocoa pod, and plantain peel ash was employed to transesterify the blend. A two-step method was adopted to convert HONOYO into methyl-esters. Taguchi L9 experimental design tool was used to ascertain the interactive effects of microwave irradiation power (W), Methanol/oil ratio (MeOH), time (min), and agro-wastes synthesized catalyst ASC (wt %) on the yield of methyl-esters from HONOYO. Results demonstrated that at 3:1 MeOH, microwave power of 150 W, ASC of 1.5 wt %, and reaction time of 1 minute, a yield of 80.96 % was achieved. HONOYOB satisfied ASTM D6751 and EN 14214 standards. Performance evaluation of the process input variables suggests weight of ASC as the most significant process parameters for HONOYOB yield. This work authenticates that biomass catalyst from agricultural wastes can adequately be applied to synthesis biodiesel effectively from blends of non-edible oils to supplement fossil diesel.
Renewable Energy Resources and Technologies
Mehdi Zare; Barat Ghobadian; Seyed Reza Hassan-Beygi; Gholamhasan Najafi
Abstract
In CI engines, the evaporation rate of fuel on various hot surfaces, including the combustion chamber, has a significant effect on deposit formation and accumulation, the exhaust emissions of PM and NOx, and their efficiency. Therefore, the evaporation of liquid fuel droplets impinging on hot surfaces ...
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In CI engines, the evaporation rate of fuel on various hot surfaces, including the combustion chamber, has a significant effect on deposit formation and accumulation, the exhaust emissions of PM and NOx, and their efficiency. Therefore, the evaporation of liquid fuel droplets impinging on hot surfaces has become an important subject of interest to engine designers, manufacturers, and researchers. The aim of this study is to investigate the evaporation characteristics based on droplet lifetime and critical surface temperature (the maximum heat transfer rate) of diesel and biodiesel fuel droplets on hot surfaces. In order to determine the effects of diesel fuel, canola oil biodiesel, and castor oil biodiesel, the droplets impinging on the hot surfaces of aluminum alloy (7075) and steel alloy (1.5920) and the evaporation lifetime of diesel and biodiesel fuels were measured. Statistical analysis (ANOVA and Duncan’s multiple-range test) was carried out using SAS software. The results showed the maximum critical surface temperature of 450 °C for the castor oil biodiesel on steel 1.5920 surface and the minimum one for diesel fuel (350 °C). In this case, both surfaces had the same droplet lifetimes of approximately 2 s. The results of ANOVA showed the significant effect of the surface material and fuel type on the evaporation lifetime of fuel droplet at 1 % probability.
Mahdi Hashemzadeh Gargari; Seyed Mojtaba Sadrameli; mohammad taherkhani
Abstract
Both the continuous and batch transesterification of linseed oil were examined in order to maximize the fatty acid methyl esters (FAME) yield. The continuous process was conducted in a packed bed reactor using calcium oxide as a heterogeneous catalyst. In addition, the impact of two variables, namely ...
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Both the continuous and batch transesterification of linseed oil were examined in order to maximize the fatty acid methyl esters (FAME) yield. The continuous process was conducted in a packed bed reactor using calcium oxide as a heterogeneous catalyst. In addition, the impact of two variables, namely the molar ratio of methanol to oil and the flow rate (ml/min), on the FAME yield were studied. Likewise, for the batch process, the reaction was carried out in a CSTR reactor using KOH as a homogeneous catalyst. Moreover, the influence of the molar ratio of methanol to oil and of catalyst concentration (wt. %) on the FAME yield was investigated. For both the batch and continuous process, FAME yield was optimized by using the Design Expert (Ver. 7.0.0) software. The optimum conditions for the continuous method were reported as follows: a molar ratio of methanol to oil of 11.75:1, a flow rate of 1.07 ml/min, and a temperature of 50oC. Under the optimum conditions, a FAME yield of 94.2423% was achieved. For the batch process, a FAME yield of 95.0672% was reached under the optimum conditions of a molar ratio of methanol to oil of 9.12:1, a catalyst concentration of 1.52 wt. %, a temperature of 40oC, an agitation rate of 650 rpm, and a reaction time of 60 minutes.
Hamid Reza Chitsaz; Mohammadreza Omidkhah; Kambiz Tahvildari
Abstract
Energy obtained from renewable sources has increased its participation in the energy matrix worldwide, and it is expected to maintain this tendency. Both in large and small scales, there have been numerous developments and research with the aim of generating fuels and energy using different raw materials ...
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Energy obtained from renewable sources has increased its participation in the energy matrix worldwide, and it is expected to maintain this tendency. Both in large and small scales, there have been numerous developments and research with the aim of generating fuels and energy using different raw materials such as alternative crops, algae and waste cooking oil. Capparis spinosa seed (containing 32% triglycerides) is used as an excellent source for biodiesel production. In this work, biodiesel (Fatty acid methyl ester) is produced by trans-esterification of Capparis spinosa oil, in the presence of methanol and sodium hydroxide as an alkaline catalyst. According to data collection, pilot of biodiesel production is simulated by using HYSYS v3.2 software. The yield of biodiesel in the presence of sodium hydroxide was considered 94%. The results of FTIR and GC-MS spectra showed trans-esterification reaction has been complete. According to the results, the produced biodiesel is in the range of ASTM Standard.
