Advanced Energy Technologies
Leila Samiee; Fatemeh Goodarzvand-Chegini; Esmaeil Ghasemikafrudi; Kazem Kashefi
Abstract
Some chemical processes, like the chlor-alkali industry, produce a considerable amount of hydrogen as by-product, which is wasted and vented to the atmosphere. Hydrogen waste can be recovered and utilized as a significant clean energy resource in the processes. This paper describes the thermodynamic ...
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Some chemical processes, like the chlor-alkali industry, produce a considerable amount of hydrogen as by-product, which is wasted and vented to the atmosphere. Hydrogen waste can be recovered and utilized as a significant clean energy resource in the processes. This paper describes the thermodynamic analysis of hydrogen recovery at an industrial chlor-alkali plant by installation of hydrogen boiler and alkaline fuel cell. In addition, emission reduction potentials for the proposed systems were estimated. However, the goal of this work is to analyze the techno-economic feasibility and environmental benefits of using utilization systems of hydrogen waste. The results showed that hydrogen boiler scenario could produce 28 ton/hr steam at pressure of 25 bar and temperature of 245 °C, whereas the alkaline fuel cell system could produce 7.65 MW of electricity as well as 3.83 m3/h of deionized water based on the whole surplus hydrogen. In comparison, the alkaline fuel cell scenario has negative IRR (Internal Return Rate) and NPV (Net Present Value) due to cheap electricity and high cost of capital investment. However, regarding the steam price, the hydrogen boiler project has reasonable economic parameters in terms of IRR and NPV. Therefore, the hydrogen recovery scenario is proposed to install a hydrogen boiler as a feasible and economic idea for steam production in our case. Furthermore, in terms of emission reduction, hydrogen boiler and alkaline fuel cell techniques can significantly reduce greenhouse gas emission by 49300 and 58800 tons/year, respectively, whereas other pollutants can also be reduced by 141 and 95 tons/year in hydrogen boiler and alkaline fuel cell scenarios, respectively.
Advanced Energy Technologies
Masoumeh Javaheri; Noushin Salman Tabrizi; Amir Rafizadeh
Abstract
Given that the catalyst and catalyst support properties have a key role to play in the electrochemical activity of fuel cells, in this research, the synergism effect of Pt and Ru nanoparticles reduced on catalyst support [synthesized Carbon Aerogel-Carbon Nanotube (CA-CNT)] was investigated. The catalyst ...
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Given that the catalyst and catalyst support properties have a key role to play in the electrochemical activity of fuel cells, in this research, the synergism effect of Pt and Ru nanoparticles reduced on catalyst support [synthesized Carbon Aerogel-Carbon Nanotube (CA-CNT)] was investigated. The catalyst support was synthesized by sol-gel method and the catalyst nanoparticles were reduced on catalyst support using impregnation and hydrothermal method. Different molar ratios of Pt:Ru (i.e., 0:1, 1:0, 3:1, 2:1, 1:1, 1:2, and 1:3) were applied as electrocatalysts for Methanol Oxidation Reaction (MOR). The electrochemical performance of these catalysts was compared with that of commercial Pt/C (20 % wt) for MOR. The physical properties of the synthesized catalyst support (CNT-CA) were studied using FESEM and BET techniques. Moreover, XRD and ICP analyses were employed for investigating each of the synthesized catalyst (Pt/CNT-CA and Ru/CNT-CA). The cyclic voltammetry and chronoamperometry methods were used to conduct electrochemical analysis. Research results indicated that synthesis methods were reliable. Moreover, CNT-CA had a proper performance as the catalyst support and the Pt:Ru with a 3:1 molar ratio was the best catalyst among all the synthesized catalysts for MOR.
Advanced Energy Technologies
Ghazanfar Shahgholian
Abstract
Renewable energy provides twenty percent of electricity generation worldwide. Hydroelectric power is the cheapest way to generate electricity today. It is a renewable source of energy and provides almost one-fifth of electricity in the world. Also, it generates electricity using a renewable natural resource ...
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Renewable energy provides twenty percent of electricity generation worldwide. Hydroelectric power is the cheapest way to generate electricity today. It is a renewable source of energy and provides almost one-fifth of electricity in the world. Also, it generates electricity using a renewable natural resource and accounting for six percent of worldwide energy supply or about fifteen percent of the world’s electricity. Hydropower is produced in more than 150 countries. Hydropower plant producers provide energy due to moving or falling water. This paper presents and discusses studies on hydroelectric power plant fields, which have been carried out by different investigators. This work aims to study and provide an overview of hydroelectric power plants such as applications, control, operation, modeling and environmental impacts. Also, the hybrid power and efficiency of the hydroelectric power plants has been investigated. The applications of a flexible AC transmission system (FACTS) controller in the power system with the hydroelectric power plants are presented.
Advanced Energy Technologies
Mahdi Shakouri; Alireza Noorpoor; Hossein Ghadamian
Abstract
In this research, an analytical method for quantification of the thermal energy performance improvement for a building integrated photovoltaic double-skin façade has provided. The system has been suggested as a retrofit measure for an existing building in Tehran. The effect of thermal performance ...
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In this research, an analytical method for quantification of the thermal energy performance improvement for a building integrated photovoltaic double-skin façade has provided. The system has been suggested as a retrofit measure for an existing building in Tehran. The effect of thermal performance has been analyzed through computer-assisted developed code using engineering equation solver software. Three scenarios have been defined and for each scenario temperature and velocity profiles have provided through continuity, momentum and energy equations. As the monocrystalline photovoltaic modules and the double-glazed windows are more conventional in the current condition in Tehran, the authors have considered them for the analysis. A comparison of results for this study is valuable for the cases intending to select between the glass and the photovoltaic as the outer façade. The quantitative results illustrate that the proposed system would be able to reduce the cooling demand in the summer case by 18.5 kilowatts, which is around 8.7 percent of the current cooling load. According to the results of the sensitivity analysis, both glass and photovoltaic façades have a greater impact in terms of energy saving in the summer case. According to the results of the analysis, by increasing the ratio between the photovoltaic outer façade to the surface area of the glass section, the amount of the energy saving due to the total cooling load reduction will increase. The results of the analysis showed that the application of the suggested system will reduce the thermal load by 2.1 percent in the winter season.
Advanced Energy Technologies
Nima Amani
Abstract
The objective of this study is to evaluate the energy efficiency of residential buildings by using natural energy and optimizing the choice of materials for heat and cold saving with the Ecotect simulation software. According to analysis and simulation was found that the optimum material of main building ...
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The objective of this study is to evaluate the energy efficiency of residential buildings by using natural energy and optimizing the choice of materials for heat and cold saving with the Ecotect simulation software. According to analysis and simulation was found that the optimum material of main building components in a mild climate zone of Rasht city is the Brick Conc block Plaster for wall with total radiation incident of 340 W/m2 and radiation absorption of 240 W/m2; Double Glazed-Low E for window with total radiation incident 340 W/m2 and radiation absorption of 100 W/m2; Foam Core Ply Wood for door with total radiation incident of 340 W/m2 and radiation absorption of 200 W/m2; ConcSlab- OnGround for floor with total radiation incident of 340 W/m2 and radiation absorption of 220 W/m2; and Conc Roof Asphalt for roof with total radiation incident of 340 W/m2 and radiation absorption of 300 W/m2. According to the hourly temperature analysis for all storeys of the building in the two hot and cold days of the year, it is determined by the design and material selection requirements that the building will be in the near thermal comfort zone (below 30 degrees) in the warm season.
Advanced Energy Technologies
Fatemeh Boshagh; Khosrow Rostami
Abstract
The current review purpose is to present a general overview of different experimental design methods that are applied to investigate the effect of key factors on dark fermentation and are efficient in predicting the experimental data for biological hydrogen production. The methods of two levels full ...
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The current review purpose is to present a general overview of different experimental design methods that are applied to investigate the effect of key factors on dark fermentation and are efficient in predicting the experimental data for biological hydrogen production. The methods of two levels full and fractional factorials, Plackett–Burman, and Taguchi were employed for screening the most important factors in dark fermentation. The techniques of central composite, Box–Behnken, Taguchi, and one factor at a time for optimization of the dark fermentation were extensively used. Papers on the three levels full and fractional factorials, artificial neural network coupled with genetic algorithm, simplex, and D-optimal for the optimization of the dark fermentation are limited, and no paper on the Dohlert design has been reported to date. The artificial neural network coupled with genetic algorithm is a more suitable method than the RSM technique for the optimization of dark fermentation. Literature shows that the optimization of critical factors plays a significant role in dark fermentation and is useful to improve the hydrogen production rate and hydrogen yield.
Advanced Energy Technologies
Sadegh Safari; Hassan Ali Ozgoli
Abstract
In this paper, an electrochemical model was developed to investigate the performance analysis of a Solid Oxide Fuel Cell (SOFC). The curves of voltage, power, efficiency, and the generated heat of cell have been analyzed to accomplish a set of optimal operating conditions. Further, a sensitivity analysis ...
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In this paper, an electrochemical model was developed to investigate the performance analysis of a Solid Oxide Fuel Cell (SOFC). The curves of voltage, power, efficiency, and the generated heat of cell have been analyzed to accomplish a set of optimal operating conditions. Further, a sensitivity analysis of major parameters that have a remarkable impact on the economy of the SOFC and its residential applications has been conducted. The results illustrate that the current density and cell performance temperature have vital effects on the system efficiency, output power and heat generation of cell of the SOFC. The best system efficiency is approached up to 53.34 % while implementing combined heat and power generation might be further improved up to 86 %. The economic evaluation results indicate that parameters such as overall efficiency, natural gas price and additional produced electricity that has prone to be sold to the national power grid, have a significant impact on the SOFC economy. The results indicate the strong reduction in the purchasing cost of the SOFC, i.e. not more than $2500, and improving the electrical efficiency of SOFC, i.e. not less than 42 %, can be the breakeven points of investment on such systems in residential applications. Also, it is found that the target of this SOFC cogeneration system for residential applications in Iran is relying on considerable technological enhancement of the SOFC, as well as life cycle improvement; improvement in governmental policies; and profound development in infrastructures to mitigate legal constraints.
Advanced Energy Technologies
Haleh Sadeghi; Iraj Mirzaei; Shahram Khalilaria; Sajad Rezazadeh; Mojtaba Rasouli Gareveran
Abstract
Among the renewable energy systems, fuel cells are of special significance about which more investigation is required. The principal goal of the present study is considering the effect of the geometry change on the fuel cell's performance. In this paper, a three-dimensional model of proton exchange membrane ...
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Among the renewable energy systems, fuel cells are of special significance about which more investigation is required. The principal goal of the present study is considering the effect of the geometry change on the fuel cell's performance. In this paper, a three-dimensional model of proton exchange membrane fuel cell has been numerically simulated with conventional cubic geometry. Afterwards, two brand-new cylindrical models have been proposed to compare and select the best model. The governing equations include mass, momentum, energy, species and electrical potential, which are discretized and solved using the method of computational fluid dynamics. The results obtained from numerical analyses were validated with those from experimental data, which showed acceptable agreement. For the above-mentioned models, changes in the species mass fraction, temperature, electric current density, and over-potential were analyzed in more detail. The results reveal that, in all three models, by decreasing the amount of cell voltage differences between the anode and the cathode, higher current density is produced, which leads to high input species consumption and, consequently, more water and heat generation. On the other hand, the four-channel cylindrical model is more efficient than the other two models and has shower pressure drop due to its shorter pathway. The results illustrated that, at V=0.6 )V(, the amount of the output current density in the four-channel model increased by approximately 18.4 %, compared to that in the other two models. Further, in this model, the material used in bipolar plates is less than that in the other models.
Advanced Energy Technologies
Azin Hasanvand; Mehdi Pourabdoli; Ahmad Ghaderi Hamidi
Abstract
The effect of Al2O3 (1-10 wt %) and Y2O3 (1-10 wt %) additions on thermochemical heat storage properties of Co3O4/CoO system was investigated by thermogravimetry, XRD, and SEM analyses. Results showed that the addition of Al2O3 to Co3O4 at constant 8 h mechanical activation improved the redox cycle stability ...
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The effect of Al2O3 (1-10 wt %) and Y2O3 (1-10 wt %) additions on thermochemical heat storage properties of Co3O4/CoO system was investigated by thermogravimetry, XRD, and SEM analyses. Results showed that the addition of Al2O3 to Co3O4 at constant 8 h mechanical activation improved the redox cycle stability and increased oxygen sorption value and rate. It was found that oxygen sorption and their rate decreased with increasing the alumina content to more than 8 wt %. The formation of the spinel phase and an increase in its amount by increasing the alumina content led to a decrease in the oxygen sorption capacity. SEM studies showed that Al2O3 prevented the sintering and particle growth of cobalt oxide particles during reduction and re-oxidation processes. In addition, results showed that the addition of Y2O3 in all ranges to Co3O4 improved the redox cycle stability of cobalt oxide; however, it significantly decreased the oxygen sorption in the Co3O4/CoO system. XRD patterns of a sample containing 10 wt % yttria before the redox process indicated the presence of only Co3O4 phase; however, after three redox cycles, other phases including CoO and Y2O3 appeared.
Advanced Energy Technologies
Ali Mostafaeipour; Mojtaba Qolipour; Hossein Goudarzi; Mehdi Jahangiri; Amir-Mohammad Golmohammadi; Mostafa Rezaei; Alireza Goli; Ladan Sadeghikhorami; Ali Sadeghi Sedeh; Seyad Rashid Khalifeh Soltani
Abstract
Fuel cells are potential candidates for storing energy in many applications; however, their implementation is limited due to poor efficiency and high initial and operating costs. The purpose of this research is to find the most influential fuel cell parameters by applying the adaptive neuro-fuzzy inference ...
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Fuel cells are potential candidates for storing energy in many applications; however, their implementation is limited due to poor efficiency and high initial and operating costs. The purpose of this research is to find the most influential fuel cell parameters by applying the adaptive neuro-fuzzy inference system (ANFIS). The ANFIS method is implemented to select highly influential parameters for proton exchange membrane (PEM) element of fuel cells. Seven effective input parameters are considered including four parameters of semi-empirical coefficients, parametric coefficient, equivalent contact resistance, and adjustable parameter. Parameters with higher influence are then identified. An optimal combination of the influential parameters is presented and discussed. The ANFIS models used for predicting the most influential parameters in the performance of fuel cells were performed by the well-known statistical indicators of the root-mean-squared error (RMSE) and coefficient of determination (R2). Conventional error statistical indicators, RMSE, r, and R2, were calculated. Values of R2 were calculated as of 1.000, 0.9769, and 0.9652 for three different scenarios, respectively. R2 values showed that the ANFIS could be properly used for yield prediction in this study
Advanced Energy Technologies
Shima Sharifi; Rahbar Rahimi; Davod Mohebbi-Kalhori; Can Ozgur Colpan
Abstract
The power density of a direct methanol fuel cell (DMFC) stack as a function of temperature, methanol concentration, oxygen flow rate, and methanol flow rate was studied using a response surface methodology (RSM) to maximize the power density. The operating variables investigated experimentally include ...
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The power density of a direct methanol fuel cell (DMFC) stack as a function of temperature, methanol concentration, oxygen flow rate, and methanol flow rate was studied using a response surface methodology (RSM) to maximize the power density. The operating variables investigated experimentally include temperature (50-75 °C), methanol concentration (0.5-2 M), methanol flow rate (15-30 ml min-1), and oxygen flow rate (900-1800 ml min-1). A new design of the central composite design (CCD) for a wide range of operating variables that optimize the power density was obtained using a quadratic model. The optimum conditions that yield the highest maximum power density of 86.45 mW cm-2 were provided using 3-cell stack at a fuel cell temperature of 75 °C with a methanol flow rate of 30 ml min-1, a methanol concentration of 0.5 M, and an oxygen flow rate of 1800 ml min-1. Results showed that the power density of DMFC increased with an increase in the temperature and methanol flow rate. The experimental data were in good agreement with the model predictions, demonstrating that the regression model was useful in optimizing maximum power density from the independent operating variables of the fuel cell stack.
Advanced Energy Technologies
Negin Maftouni; Minoo Askari
Abstract
Both energy and environmental criticisms push a society toward energy-efficient buildings with green technologies. Green roofs are of significant importance due to their remarkable role in decreasing the thermal loads ofbuildings, especially in summer, and also in sound insulation. Here in, the thermal ...
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Both energy and environmental criticisms push a society toward energy-efficient buildings with green technologies. Green roofs are of significant importance due to their remarkable role in decreasing the thermal loads ofbuildings, especially in summer, and also in sound insulation. Here in, the thermal loads of a residential building were calculated, and then, an optimized green roof was designed for it in three different cities of Tehran, Rasht, and Tabriz. The energy saving was analyzed in each case, and proper plants and roof thickness were selected to achieve both comfortable air conditioning and energy optimization. It is also important to use water resources in an optimized manner. Considering the annual mean rain magnitude, here, a suitable system is designed to harvest rainwater for watering the plants. Results indicate that a sedum grass-based green roof with the thickness of 10 cm leads to a 21.3 % reduction in the annual total thermal loads in Tehran; one with thickness of 8 cm in Tabriz will result in a 11.7 % thermal load reduction per year; a green roof with 9 cm thickness in Rasht, Iran shows 13.2 % energy saving per year. Therefore, Tehran is the best option here to integrate the green roof into the structure of the building. The patterns of the obtained data indicate that the reduction of cooling loads is more noticeable when implementing a green roof in comparison with heating loads. Moreover, it has been revealed that harvested rainwater is sufficient to support about 72 % of required water in Tehran, 81 % of it in Tabriz, and 93 % in Rasht.
Advanced Energy Technologies
Ashkan Nahvi Bayani; Mohammad Hadi Moghim; Saeed Bahadorikhalili; Abdolmajid Ghasemi
Abstract
Despite the extensive use of polyolefins, especially in the form of lithium-ion battery (LIB) separators, their flammability limits their large-scale battery applications. Therefore, the fabrication of flame-retardant LIB separators has attracted much attention in recent years. In this work, composite ...
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Despite the extensive use of polyolefins, especially in the form of lithium-ion battery (LIB) separators, their flammability limits their large-scale battery applications. Therefore, the fabrication of flame-retardant LIB separators has attracted much attention in recent years. In this work, composite separators were fabricated by applying a ceramic-based composite coating composed of a metal hydroxide as a filler and flame-retardant agent (Aluminium hydroxide, Al(OH)3) and a binder (Poly(vinylidene Fluoride-co-hexafluoropropylene), P(VDF-HFP)) to the polypropylene (PP) commercial separator. Thermal shrinkage, thickness, air permeability, porosity, wettability, ionic conductivity, flame retardancy, and electrochemical performance of the fabricated ceramic-coated composite separator were investigated. The results showed that the addition of Al(OH)3 particles improved thermal shrinkage ( 8 %) and flame retardancy of the commercial separator, which can prevent dimensional changes at high temperatures and significantly increase LIBs safety. Applied 11 µm ceramic-based coating layer on PP commercial separator had 76 % porosity that increased the value of air permeability from 278.15 (s/100 cc air) to 312.8 (s/100 cc air), causing much facile air permeation through the pores of commercial separator than the composite one. Furthermore, suitable electrolyte uptake and the contact angle of ceramic coated separator (135 % and 91.19°, respectively) facilitated ion transport through the pores, which effectively improved the ionic conductivity of Al(OH)3-coated PP separator (about 1.4 times higher than bare separator). Moreover, the cell comprising Al(OH)3-coated PP separator had better cyclic performance than that of bare PP separator. All these characteristics make the fabricated flame-retardant Al(OH)3 composite separator an appropriate candidate to ensure the safety of the large-scale LIB.
Advanced Energy Technologies
Mohammad Sajjad Rostami; Morteza Khashehchi; Payam Zarafshan; Mohammad Hossein Kianmehr; Ehsan Pipelzadeh
Abstract
Capacitive deionization (CDI) is an emerging energy efficient, low-pressure and low-cost intensive desalination process that has recently attracted experts’ attention. The process is to explain that ions (cations and anions) can be separated by a pure electrostatic force imposed by a small bias ...
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Capacitive deionization (CDI) is an emerging energy efficient, low-pressure and low-cost intensive desalination process that has recently attracted experts’ attention. The process is to explain that ions (cations and anions) can be separated by a pure electrostatic force imposed by a small bias potential. Even at a rather low voltage of 1.2 V, desalinated water can be produced. The process can be well operational by a professional cell design. Although various processes have been manufactured before, in this study, membrane was removed and a new unit was designed and manufactured (Using CFD Simulation). In this case, the combination of activated carbon powder (with an effective surface area of 2600 m2 per gram), carbon black, and polyvinyl alcohol with a ratio of 35/35/30 coated on carbon paper as electrode materials was considered for tests. The weight was 1.41 grams for each material, and the thickness was 0.44 mm. CDI system was tested, and the results of charge-discharge cycles, cyclic voltammetry, and impedance spectroscopy were evaluated. It can be implied that there is no need for a strong pump and, also, pressure drop can be reduced due to such a noticeable space between two electrodes. Preliminary experimental results showed high specific capacitance (2.1 Farad) and ultra-high salt adsorption capacity, compared with similar cases.
Advanced Energy Technologies
Vajihe Yousefi; Davod Mohebbi-Kalhori; Abdolreza Samimi
Abstract
The effect of the thickness of ceramic membrane on the productivity of microbial fuel cells (MFCs) was investigated with respect to the electricity generation and domestic wastewater treatment efficiencies. The thickest ceramic membrane (9 mm) gained the highest coulombic efficiency (27.58±4.2 ...
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The effect of the thickness of ceramic membrane on the productivity of microbial fuel cells (MFCs) was investigated with respect to the electricity generation and domestic wastewater treatment efficiencies. The thickest ceramic membrane (9 mm) gained the highest coulombic efficiency (27.58±4.2 %), voltage (681.15±33.1 mV), and current and power densities (447.11±21.37 mA/m2, 63.82±10.42 mW/m2) compared to the 6- and 3-mm thick separators. The results of electrochemical impedance spectroscopy (EIS) analysis were investigated to identify the internal resistance constituents by proposing the appropriate equivalent electrical circuit. The Gerischer element was modeled as the coupled reaction, and diffusion in the porous carbon electrodes and the constant phase element was assimilated into the electrical double-layer capacitance. The thickest ceramic (9 mm) was found to have the largest ohmic resistance; however, owing to its superior barrier capability, it provided more anoxic conditions for better accommodation of exoelectrogenic bacteria in the anode chamber. Therefore, lower charge transfer, fewer diffusional impedances, and higher rates of anodic reactions were achieved. Excessive oxygen and substrate crossover through the thinner ceramics (of 6 and 3 mm) resulted in the suppressed development of anaerobic anodic biofilm and the accomplishment of aerobic substrate respiration without electricity generation.
Advanced Energy Technologies
Mohammad Jafari; Hossein Ghadamian; Leila Seidabadi
Abstract
The study of the battery charge process as the only power storage agent in off-grid systems is of significant importance. The battery charge process has different modes, and the battery in these modes is dependent on the amount of charge. In order to charge the battery in off-grid systems, two charge ...
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The study of the battery charge process as the only power storage agent in off-grid systems is of significant importance. The battery charge process has different modes, and the battery in these modes is dependent on the amount of charge. In order to charge the battery in off-grid systems, two charge controllers including Pulse Width Modulation (PWM) and Maximum Power Point Tracker (MPPT) are commonly used. The charge rate (C-Rate) is different in these two models. Therefore, it is necessary to study the state of charge (SoC) in the PWM and MPPT models considerably. In this study, by using these two charge controller models, C-Rate is examined on portable and power plant scales. This research indicates that the PWM charge controller has better performance on the power plant scale than on the portable scale. The charging quality of the MPPT model is about 31 % and 7 % on portable and power plant scales, respectively, proved to be higher than that of the PWM charge controller. The PV panel performance has increased by 2 %-5 % through the application of the MPPT charge controller, compared with the PWM model. As the overall achievement of the experiment, according to the limitations of the MPPT charge controller, the PWM charge controller can be proposed on power plant scales, whereas the application of the MPPT model is appropriate for specific purposes.
Advanced Energy Technologies
Mohammad Zarei-Jelyani; Shaghayegh Baktashian; Mohsen Babaiee; Rahim Eqra
Abstract
In recent years, many studies have focused on the active materials of anodes to improve the performance of LIBs, while limited attention has been given to polymer binders, which act as inactive ingredients. However, polymer binders have amazing influence on the electrochemical performance of anodes. ...
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In recent years, many studies have focused on the active materials of anodes to improve the performance of LIBs, while limited attention has been given to polymer binders, which act as inactive ingredients. However, polymer binders have amazing influence on the electrochemical performance of anodes. Herein, to investigate the binding performance between MCMB artificial graphite and the copper current collector, three binders such as PVDF, MSBR, and CMC+SBR were used to prepare the anode electrodes. The mechanical and electrochemical tests were conducted for different MCMB electrodes. The results show that the water-based binders (CMC+SBR and MSBR) made better adhesion properties for the coating on the current collector in comparison with the organic solvent-based binder (PVDF). MCMB anode fabricated with CMC+SBR binder shows the highest discharge capacity and the best rate performance at various C-rates of 0.2C, 0.5C, and 1C that result in the brilliant electrochemical performance. Therefore, artificial graphite anode materials using cheap aqueous CMC+SBR binder instead of toxic solvent like NMP and expensive PVDF improve electrochemical property and reduce the cost of LIBs.
Advanced Energy Technologies
Imad-Eddine Fahs; Majid Ghasemi
Abstract
Converting chemical energy into electricity is done by an electro-chemical device known as a fuel cell. Thermal stress is caused at high operating temperature between 700 oC to 1000 oC of SOFC. Thermal stress causes gas escape, structure variability, crack initiation, crack propagation, and cease operation ...
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Converting chemical energy into electricity is done by an electro-chemical device known as a fuel cell. Thermal stress is caused at high operating temperature between 700 oC to 1000 oC of SOFC. Thermal stress causes gas escape, structure variability, crack initiation, crack propagation, and cease operation of the SOFC before its lifetime. The aim of this study is to present a method that predicts the initiation of cracks in an anisotropic porous planar SOFC. The temperature and stress distribution are calculated. The code uses the generated data, stress intensity factor, and the J-integral of the materials to predict the initiation of the crack inside the porous anode and cathode. The results show that the highest thermal stress occurs at the upper corners of cathode and at the lower corners of the anode. In addition, the thickness of cathode electrode on the left side is increased by 1.5 %. Finally, the crack initiation occurs on the left side between the upper and lower corners of the cathode.
Advanced Energy Technologies
Maryam Rahmani; Faramarz Faghihi; Hassan Moradi CheshmehBeigi; Seyed Mehdi Hosseini
Abstract
In this paper, the effect of a static synchronous compensator (STATCOM) influence on the frequency of islanded microgrids based on frequency control using fuzzy cooperative control is investigated. To achieve fast frequency control, instantaneous power balance between generation and consumption is inevitable, ...
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In this paper, the effect of a static synchronous compensator (STATCOM) influence on the frequency of islanded microgrids based on frequency control using fuzzy cooperative control is investigated. To achieve fast frequency control, instantaneous power balance between generation and consumption is inevitable, and it can be supplied through energy storage systems such as battery with a proper frequency control method. Besides, the frequency control of islanded microgrids could be studied under different circumstances, where one aspect analyzed is added to a flexible AC transmission system (FACTS) device, such as STATCOM, in the microgrids. Although STATCOM is charged with improving the voltage profile, it can affect frequency stability by adjusting the voltage very quickly. Due to the importance of refining frequency stability, two controller methods are compared: a classic PI controller and a fuzzy PID controller. Accordingly, the performance of STATCOM is evaluated via two scenarios. Based on simulation results, by applying the fuzzy PID controller to the microgrid, STATCOM can reach the nominal frequency. Moreover, with greater validation and investigation of this topic, this device could be an agreeable alternative to the battery energy storage system (BESS).
Renewable Energy Resources and Technologies
Negin Maftouni; Kiana Motaghedi
Abstract
Traditional fossil fuels, which are also depleting cause environmental problems. A significant portion of global energy consumption is due to building air conditioning systems. Nowadays, considerable attention is drawn to renewable and sustainable energy sources to support the energy requirements of ...
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Traditional fossil fuels, which are also depleting cause environmental problems. A significant portion of global energy consumption is due to building air conditioning systems. Nowadays, considerable attention is drawn to renewable and sustainable energy sources to support the energy requirements of buildings. In this study, a solar absorption chiller was designed for a three-floor residential building in hot and arid climate. At first, thermal loads in the building were calculated using Carrier software. The material and color of the exterior walls, as well as window types, were changed to reduce the heat transfer coefficient and get an optimum design. Results indicate that by using the optimum design, maximum heating load reduction and maximum cooling load reduction can be achieved with approximate rates of 37 % and 12 %, respectively. Considering safety factor and based on the maximum cooling load, a single-effect LiBr-water solar absorption chiller was designed for the optimum building. Two different scenarios were suggested using two types of flat plate and evacuated tube collector. Results show that in the case of evacuated tube collector the net collector area of 254.18 m2 is sufficient to supply the cooling power. Implementing flat plate collectors would result in occupying an area of 398.5 m2. Regarding the limitation of total area of roof and efficiency issues, the evacuated tube collector is the best option.
Advanced Energy Technologies
Mohammad Zarei-Jelyani; Mohammad Sarshar; Mohsen Babaiee; Nima Tashakor
Abstract
Accurate lifetime prediction of lithium-ion batteries is a great challenge for the researchers and engineers involved in battery applications in electric vehicles and satellites. In this study, a semi-empirical model is introduced to predict the capacity loss of lithium-ion batteries as a function ...
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Accurate lifetime prediction of lithium-ion batteries is a great challenge for the researchers and engineers involved in battery applications in electric vehicles and satellites. In this study, a semi-empirical model is introduced to predict the capacity loss of lithium-ion batteries as a function of charge and discharge cycles, operational time, and temperature. The model parameters are obtained by minimizing the prediction errors of experimental capacity loss for each charge/discharge cycle at 25 oC, 35 oC, and 45 oC.The optimum values of the model parameters are obtained using genetic algorithm, one of the optimization tools in Matlab software. The model accurately predicts the capacity loss of lithium-ion battery for more charge and discharge cycles at 25 °C with an average error of 4 %. The mentioned cycles are used only to validate the prediction.
Advanced Energy Technologies
Hassan Ali Ozgoli
Abstract
Fuel cell-based hybrid cycles that include conventional power generators have been created to modify energy performance and output power. In the present paper, integrated biomass gasification (IBG)-molten carbonate fuel cell (MCFC)-gas turbine (GT) and steam turbine (ST) combined power cycle is introduced ...
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Fuel cell-based hybrid cycles that include conventional power generators have been created to modify energy performance and output power. In the present paper, integrated biomass gasification (IBG)-molten carbonate fuel cell (MCFC)-gas turbine (GT) and steam turbine (ST) combined power cycle is introduced as an innovative technique in terms of sustainable energy. In addition, biomass gasification has been explained and shown able to supply the required fuel to the energy generators to compensate for the consumption consequences of fossil fuels. In this system, a molten carbonate fuel cell generates electricity from syngas produced by biomass gasification. In addition, a gas cleaning process prepares adequate treatment before consumption in the fuel cell. Furthermore, for the justification of this system as a combined heat and power (CHP) cycle, a considerable amount of produced heat in the proposed process generates power in GT and ST bottoming cycles. Due to the energy targeting, modeling and simulation of the presented system were fulfilled by the Cycle-Tempo software, and the results showed about 42 MW output power and total efficiency of around 83 %. Further to that, parametric studies represented the durability of the generated power against ambient temperature variations. Finally, changes in total power and efficiency due to the fluctuation of the moisture content of biomass, pressure ratio, and inlet temperature of GT have also been demonstrated.
Advanced Energy Technologies
Tamer Nabil; Mohamed Khairat Dawood; Tamer Mansour
Abstract
Since the renewable resources of energy have become extremely important, especially wind energy, scientists have begun to modify the design of the wind turbine components, mainly rotor blades. Aerodynamic design considered a major research field related to power production of a small horizontal wind ...
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Since the renewable resources of energy have become extremely important, especially wind energy, scientists have begun to modify the design of the wind turbine components, mainly rotor blades. Aerodynamic design considered a major research field related to power production of a small horizontal wind turbine, especially in low wind speed locations. This study displays an approach to the selection of airfoil and blade design utilized in small horizontal wind turbines with low cut-in speed and with no gear box. Modeling of the flow depends on Computational Fluid Dynamics (CFD) and theory of Blade Element Momentum (BEM) methodologies. QBlade used (BEM) for wind turbine simulation and integrated with XFOIL for airfoils design to ensure the requested characteristics for wind turbine performance. MATLAB is used to calculate the final design parameters to be modeled in SOLIDWORK. The flow dynamics are explored with the aid of ANSYS Fluent 16. The application of specially designed blades grants start up at lower wind speeds. The designed blade is fabricated from polyurethane foam. Experimental study confirmed that, at low average wind velocity (4m/s), the fabricated small-scale horizontal wind turbines are considered to be a positive way to supply electricity with an average power rate of 9watt and efficiency of 8%.
Advanced Energy Technologies
Tuhid Pashaee Golmarz; Sajad Rezazadeh; Narmin Bagherzadeh
Abstract
In this paper, a three-dimensional, single-phase proton-exchange membrane fuel cell (PEMFC) is studied numerically. Finite volume method was used for solving the governing equations and, consequently, the numerical results were validated by comparing them with experimental data, which showed good agreement. ...
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In this paper, a three-dimensional, single-phase proton-exchange membrane fuel cell (PEMFC) is studied numerically. Finite volume method was used for solving the governing equations and, consequently, the numerical results were validated by comparing them with experimental data, which showed good agreement. The main objective of this work is to investigate the effect of a novel gas channel shape– by applying sinusoidal gas channel- on the cell performance and mass transport phenomena. Some parameters such as oxygen consumption, water production, protonic conductivity, and temperature distribution for two cell voltages were studied, and the results were compared with respect to conventional and new models. The results indicated that the new novel model showed better performance than the conventional model, especially at low cell voltages, causing an increase in oxygen consumption and water production. Therefore, based on a number of investigated relations, a higher rate of current density was obtained, thus enhancing the fuel cell performance. This is because the incoming species path to the gas channels in the new model becomes longer. Therefore, the diffusion of the species toward the electrochemical reaction area increased.
Advanced Energy Technologies
Marzieh Moein; Somayeh Pahlavan; Mehdi Jahangiri; Akbar Alidadi Shamsabadi
Abstract
The electricity economy and its excessive consumption have become one of the main concerns of the Iranian government for many years. This issue, along with recent droughts, shows the need to use renewable energy that is free and clean and does not require water. In addition, due to the high cost of cable-laying ...
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The electricity economy and its excessive consumption have become one of the main concerns of the Iranian government for many years. This issue, along with recent droughts, shows the need to use renewable energy that is free and clean and does not require water. In addition, due to the high cost of cable-laying and maintenance of power lines, it is not at all an option at all distances over the development of the national electricity grid. Therefore, it is important to find a distance for farther distances so that the use of renewable energy systems can be superior to the national electricity grid. According to related studies conducted so far, nothing has been done in this regard in Iran untill private-sector investors realize that, for what distances from the national grid, the network development is not cost-effective compared to using renewables. Therefore, in the present work, by using NASA's wind and solar data, 102 stations in Iran were investigated using the HOMER software. The studied system is a solar-wind one backed up by batteries and diesel generator for emergency conditions. The results showed that the average total net present cost of the solar-wind hybrid system in Iran was to provide a daily average electricity load of 5.9 kWh of a residential building with a peak load of 806 W equal to $ 12415, which could on average provide 95.3% of the building's needs by renewable energy. The average minimum distance from the national grid is 593 m for the cost-effective use of renewable energy.
