Renewable Energy Resources and Technologies
Ayowumi Rita Soji-Adekunle; Betiku Eriola; Abraham A. Asere
Abstract
This study used ternary substrates consisting of honne, neem, and yellow oleander (HONOYO) oil blend to produce methyl-esters for sustainability of raw materials for biodiesel synthesis. A biomass-based catalyst from calcined mixed agro-wastes consisting of kolanut pod, cocoa pod, and plantain peel ash ...
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This study used ternary substrates consisting of honne, neem, and yellow oleander (HONOYO) oil blend to produce methyl-esters for sustainability of raw materials for biodiesel synthesis. A biomass-based catalyst from calcined mixed agro-wastes consisting of kolanut pod, cocoa pod, and plantain peel ash was employed to transesterify the blend. A two-step method was adopted to convert HONOYO into methyl-esters. Taguchi L9 experimental design tool was used to ascertain the interactive effects of microwave irradiation power (W), Methanol/oil ratio (MeOH), time (min), and agro-wastes synthesized catalyst ASC (wt %) on the yield of methyl-esters from HONOYO. Results demonstrated that at 3:1 MeOH, microwave power of 150 W, ASC of 1.5 wt %, and reaction time of 1 minute, a yield of 80.96 % was achieved. HONOYOB satisfied ASTM D6751 and EN 14214 standards. Performance evaluation of the process input variables suggests weight of ASC as the most significant process parameters for HONOYOB yield. This work authenticates that biomass catalyst from agricultural wastes can adequately be applied to synthesis biodiesel effectively from blends of non-edible oils to supplement fossil diesel.
Renewable Energy Resources and Technologies
Marziyeh Gharibian; Bahram Hosseinzadeh Samani; Alireza Shirneshan; Sajad Rostami
Abstract
To investigate the possibility of using fuel for plant origin in a diesel generator, safflower methyl ester was prepared and used as a biodiesel. In this research, biodiesel was produced through a transesterification reaction using a hydrodynamic reactor, which increased the reaction efficiency and reduced ...
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To investigate the possibility of using fuel for plant origin in a diesel generator, safflower methyl ester was prepared and used as a biodiesel. In this research, biodiesel was produced through a transesterification reaction using a hydrodynamic reactor, which increased the reaction efficiency and reduced fuel production time. Upon increasing the reaction time from 30 seconds to 60 seconds, the reaction performance increased by 5.5 %. Then, its important features complied with ASTM D-6751 standard. The performance and pollution indices of the diesel generator engine were tested with compounds B0, B20, B50, B80 and B100. The results of short-term engine tests showed that by increasing the share of biodiesel to 20 %, CO emissions were reduced by 21 % compared to pure diesel fuel, but the amount of NOX increased by 0.82 % compared to diesel. Also, the use of 20 % volume of biodiesel in the fuel composition increased the thermal efficiency of braking, braking power, and braking torque of fuel, compared to diesel. Also, the specific fuel consumption of B20 was reduced by 2 %, which is very important economically. Finally, the TOPSIS analysis illustrated that B50 fuel outperformed pure diesel fuel and other listed fuel combinations.
Environmental Impacts and Sustainability
Bahram Hosseinzadeh Samani; Marziyeh Ansari Samani; Rahim Ebrahimi; Zahra Esmaeili; Ali Ansari Ardali
Abstract
Due to limited oil reserves, the rising world fuel prices and environmental problems caused by the use of fossil fuels increase the tendency to use alternative fuels such as biodiesel and bioethanol. In this study, the evaluation of energy and exergy flow from seed planting to final production of biodiesel ...
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Due to limited oil reserves, the rising world fuel prices and environmental problems caused by the use of fossil fuels increase the tendency to use alternative fuels such as biodiesel and bioethanol. In this study, the evaluation of energy and exergy flow from seed planting to final production of biodiesel from rapeseed oil was carried out. Biodiesel production from rapeseed was made in three main phases: farm, oil extraction, and industrial biodiesel production. Initially, the input and output variables for rapeseed production were collected through questionnaires from 30 rapeseed farms in Khuzestan province, Iran. Thus, the amount of energy input and output to the field for rapeseed was estimated to be 12826.98 and 22195 MJ/ha, respectively. The highest energy consumption is related to chemical fertilizers with 65 % share of other inputs. Input and output exergy rates were obtained as 3933.494 and 22603.39 MJ/ha, respectively, and the highest exergy consumption related to diesel fuel with 58 % share of other inputs. At the biodiesel production stage, the input energy and output energy were 156.95 MJ and 41.88 MJ, respectively, and the highest amount of electricity consumed was 91.02 MJ. The total amount of exergy in the production of biodiesel and the output exergy was 48.412 MJ and 64.568 MJ, respectively. In this study, the effects of alcohol-to-oil molar ratio, ultrasound power (W), catalyst concentration (w/w %), and the reaction time (min) on methyl ester yield using response surface methodology based on Box Behnken experimental design in the Design Expert software were investigated. Finally, gas emissions were studied at the planting and biodiesel production stages, and the resultsshowed that the highest greenhouse gas emissions at the planting stage were related to chemical fertilizers and alcohol production.
Renewable Energy Resources and Technologies
Alireza Shirneshan; Bahram Hosseinzadeh Samani
Abstract
In this study, the effects of JP-4-biodiesel-diesel blends and engine operating parameters on the performance characteristics of a diesel engine were investigated. The experimental tests were performed on a four-cylinder DI diesel engine. The Mixture-RSM method was applied to develop the mathematical ...
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In this study, the effects of JP-4-biodiesel-diesel blends and engine operating parameters on the performance characteristics of a diesel engine were investigated. The experimental tests were performed on a four-cylinder DI diesel engine. The Mixture-RSM method was applied to develop the mathematical models based on the experimental data. The results showed that the fitted models could be properly applied to predict the performance characteristics of the engine. According to the results, the brake power and torque decreased with increasing the biodiesel amount in the fuel mixture due to the lower energy content and higher viscosity of biodiesel than diesel fuel No.2. However, the brake power and torque increased slightly with increasing JP-4 in the fuel blend. The results also indicated that the BSFC increased with the higher proportion of biodiesel in the mixture at all engine speeds. The results indicated that there was no considerable difference in BSFC values while JP-4 was added to the fuel mixture, especially at higher engine speeds. Moreover, the difference of brake power values for fuel blends included biodiesel and neat diesel decreases at higher engine speeds due to the positive role of oxygen content in the molecular structure of biodiesel. Based on the results, brake power and torque increased at the higher engine load as a result of higher temperatures and better combustion conditions. Moreover, JP-4 caused an improvement in brake thermal efficiency compared to biodiesel, especially at lower and medium engine speeds. Generally, it is indicated that the application of JP-4 can improve engine performance.
Renewable Energy Resources and Technologies
Tazkieh Gilvari; Behzad Aghabarari; Mohammad Pazouki
Abstract
This study investigated the esterification reaction of different carboxylic acids (Acetic acid, Palmitic acid, and Oleic acid) and ethanol by ZnO, Al2O3-ZnOmixed oxide, and phosphotungestic acid (10 wt %) immobilized on the Al2O3-ZnOmixed oxide. The heterogeneous catalysts were characterized by XRD, ...
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This study investigated the esterification reaction of different carboxylic acids (Acetic acid, Palmitic acid, and Oleic acid) and ethanol by ZnO, Al2O3-ZnOmixed oxide, and phosphotungestic acid (10 wt %) immobilized on the Al2O3-ZnOmixed oxide. The heterogeneous catalysts were characterized by XRD, BET, FE-SEM, and EDX techniques. Optimum yield was achieved by using 10 % HPW/Al2O3-ZnOas the best catalyst, and the effects of the amount of catalyst, molar ratio of acid to alcohol, reaction temperature, and time were investigated to ensure the ideal yield of esterification reaction of acetic acid and ethanol. The results showed that the esterification of acetic acid to its ethyl ester was carried out in 3.5 hours, with an alcohol-to-acid-molar ratio of 2 and a temperature of 80 ˚C with yield 98 %. Moreover, the 10 % HPW/Al2O3-ZnOcatalystshowed well activity in biodiesel production by the esterification of palmitic and oleic acids and the reaction yield did not decrease with an increase in alkyl chain lengthin acid molecules, remarkably.
Environmental Impacts and Sustainability
Marziyeh Forootan; Bahram Hosseinzadeh Samani; Amin Lotfalian; Sajad Rostami; Zahra Esmaeili; Marziyeh Ansari Samani
Abstract
To preserve fossil fuel sources and reduce environmental pollution, it is necessary to use higher quality and more efficient fuels that cause lower pollution and are recovered more easily. Therefore, this study will investigate the cycle of biodiesel production from chicken fat by life-cycle assessment ...
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To preserve fossil fuel sources and reduce environmental pollution, it is necessary to use higher quality and more efficient fuels that cause lower pollution and are recovered more easily. Therefore, this study will investigate the cycle of biodiesel production from chicken fat by life-cycle assessment (LCA). To achieve this purpose, information on the amount of inputs consumed and produced by some broiler-farming units was collected using questionnaire. The value of net energy in this cycle was assessed to be a large negative number, and the energy ratio lower than one indicates high energy consumption of the production of this fuel. The net yield of biodiesel production was 0.574 liter-biodiesel per kg of waste fat. In the cycle, the greatest impact of pollutants was exerted on the Marine aquatic ecotoxicity intoxication and the least effect on ozone depletion. According to the global warming index, production of 1 liter of biodiesel yielded 1.90 kg CO2, and the depletion rate of fossil fuel sources for the production of 1 liter of biodiesel was obtained 21.35 MJ. The production of biodiesel from chicken slaughterhouse waste fat is considered a kind of energy recycling and is an effort to reduce environmental pollution.
Mohammad Kord; Seyed Mojtaba Sadrameli; Barat Ghobadian
Abstract
The purpose of this research work was to investigate the optimum operating conditions for biodiesel production from castor oil using a microwave. The Box–Behnken design of experiment was carried out using the Design Expert 7. A response surface methodology (RSM) was used to analyze the influence ...
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The purpose of this research work was to investigate the optimum operating conditions for biodiesel production from castor oil using a microwave. The Box–Behnken design of experiment was carried out using the Design Expert 7. A response surface methodology (RSM) was used to analyze the influence of the process variables (molar ratio of methanol to castor oil, catalyst concentration, reaction time, and microwave power) on the biodiesel yield. Optimizing biodiesel production reaction based on the yield of reaction by means of response surface method showed that 1.44 wt.% of catalyst concentration, 7.12:1 molar ratio of alcohol to oil, microwave power of 500 W and 120 seconds of reaction time produces the best results for maximizing the conversion percent. Finally, Biodiesel samples were analyzed with Gas Chromatography (GC) method for determination of fatty acid methyl ester yield. The yield of reaction obtained was 92.15% with above operating conditions and temperature of output flow was 58 oC.
Behzad Aghabarari
Abstract
In this study, Functionalized chitosan with amine groups was synthesized and coated on the surface of carbon black. The hybrid amino functionalized chitosan-carbon support was employed as an efficient, environmentally friendly heterogeneous catalyst for the transesterification reaction of canola oil ...
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In this study, Functionalized chitosan with amine groups was synthesized and coated on the surface of carbon black. The hybrid amino functionalized chitosan-carbon support was employed as an efficient, environmentally friendly heterogeneous catalyst for the transesterification reaction of canola oil and methanol. It was observed that this hybrid was more active than parent polymer at the reaction condition. Furthermore, the reactionparameters, such as reaction temperature, molar ratio, amount of the catalyst and reaction time were studied. It was shown that the conversion of canola oil to methyl esters could reach to 95 % during 3.5 h when the reaction was performed with the molar ratio of methanol to canola oil of 12, a catalyst amount of 5 Wt.%, at the reaction temperature of 60 C. These results can be explained by the inherent basicity of amines groups of amino functionalized chitosan on the surface of carbon support. This novel heterogeneous catalyst offers several attractive advantages such as high catalyst activity, easy recovery and reusability of the catalyst.
Hamid Reza Chitsaz; Mohammadreza Omidkhah; Kambiz Tahvildari
Abstract
Energy obtained from renewable sources has increased its participation in the energy matrix worldwide, and it is expected to maintain this tendency. Both in large and small scales, there have been numerous developments and research with the aim of generating fuels and energy using different raw materials ...
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Energy obtained from renewable sources has increased its participation in the energy matrix worldwide, and it is expected to maintain this tendency. Both in large and small scales, there have been numerous developments and research with the aim of generating fuels and energy using different raw materials such as alternative crops, algae and waste cooking oil. Capparis spinosa seed (containing 32% triglycerides) is used as an excellent source for biodiesel production. In this work, biodiesel (Fatty acid methyl ester) is produced by trans-esterification of Capparis spinosa oil, in the presence of methanol and sodium hydroxide as an alkaline catalyst. According to data collection, pilot of biodiesel production is simulated by using HYSYS v3.2 software. The yield of biodiesel in the presence of sodium hydroxide was considered 94%. The results of FTIR and GC-MS spectra showed trans-esterification reaction has been complete. According to the results, the produced biodiesel is in the range of ASTM Standard.
Sajad Rostami; Bahram Hosseinzadeh Samani; Keramatolah Saeidi
Abstract
Renewable energy sources are developed worldwide, owing to high oil prices and in order to limit greenhouse gas emissions. The objective of this research was to study the feasibility of biodiesel production from mountain almond (Prunus Scoparia) oil using ultrasonic system and optimization of the process ...
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Renewable energy sources are developed worldwide, owing to high oil prices and in order to limit greenhouse gas emissions. The objective of this research was to study the feasibility of biodiesel production from mountain almond (Prunus Scoparia) oil using ultrasonic system and optimization of the process using Artificial Bees Colony (ABC) Algorithm. The results showed that by increasing the molar ratio, the conversion percentage increased and after reaching a certain ratio, further increase in the molar ratio caused decrease in the conversion percentage. Increasing in the ultrasound amplitude resulted in an increase in the conversion percentage which tends to ascend; Furthermore, results of optimization showed that the amount of molar ratio, amplitude, pulse and reaction time were 5.6, 0.90, 0.33 and 5 min, respectively. For independent variables, the values of yield and energy consumption were obtained which were equal to 96.1% and 9912 J, respectively. This finding proves that ABC algorithm can estimate the optimum point in biodiesel production with high accuracy. Renewable energy sources are developed worldwide, owing to high oil prices and in order to limit greenhouse gas emissions. The objective of this research was to study the feasibility of biodiesel production from Mountain almond (Prunus scoparia) oil using ultrasonic system and optimization of the process using Artificial Bees Colony Algorithm. The results showed that with increasing the molar ratio, the conversion percentage increased and after reaching a certain ratio, further increase in the molar ratio caused decrease in the conversion percentage. The increase in the ultrasound amplitude resulted in an increase in the conversion percentage which tends to ascend. Furthermore, results of optimization showed that the amount of molar ratio, amplitude, pulse and reaction time were 5.6, 0.90 0.33 and 5 min, respectively. For independent variables, the values of yield and energy consumption were obtained which were equal to 96.1% and 9912 J, respectively. This finding proves that ABC algorithm can estimate the optimum point in biodiesel production with high accuracy.
