Renewable Energy Resources and Technologies
Abdurrahman Abubakar; Madihah Binti MD Salleh; Adibah Binti Yahya; Chong Chun Shiong; Shaza Eva Mohamad; Suraini Abd-Aziz Binti Abd-Aziz; Huszalina Hussin
Abstract
Oil Palm Frond (OPF) juice has been the focus of Malaysian bioenergy producers through acetone-butanol-ethanol (ABE) fermentation. However, due to the high concentration of phenolic compounds in the hydrolysate, usually gallicacid and ferulic acids, the fermentation medium turns acidic which hinders ...
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Oil Palm Frond (OPF) juice has been the focus of Malaysian bioenergy producers through acetone-butanol-ethanol (ABE) fermentation. However, due to the high concentration of phenolic compounds in the hydrolysate, usually gallicacid and ferulic acids, the fermentation medium turns acidic which hinders the growth of most microorganisms. A suitable method of phenolic compound removal with a minimal effect on the sugar stability of OPF juice has been employed using Amberlite XAD-4 resin. During the detoxification process, the effects of temperature and pH on the removal of phenolic compounds and sugar stability were also assessed. The Amberlite XAD-4 resin managed to adsorb about 32% of phenolic compound from the OPF hydrolysate at an optimum temperature of 50 °C and hydrogen ion concentration (pH) of 6. In addition, it maintained as much as 93.7 % of the sugar in the OPF juice. The effect of detoxifying OPF hydrolysate was further tested for biobutanol production in batch culture using strain Clostridium acetobutylicum SR1, L2, and A1. Strain L2 gave the highest improvement in biobutanol and total solvent production by 22.7% and 14.41%, respectively, in medium with detoxified OPF juice. Meanwhile, compared to non-detoxified OPF juice, the acid production of strain L2 significantly decreased by 2.99-fold when using detoxified OPF juice, despite a 1.2-fold increase in sugar consumption. Conclusively, using Amberlite XAD-4 resin to detoxify OPF hydrolysate at pH 6 and 50 °C removed the phenolic compound while increasing the strain L2 capability to improve biobutanol and total solvent production.
Advanced Energy Technologies
Payam Ghorbannezhad; Maryam Abbasi
Abstract
Fast pyrolysis of sugarcane bagasse was investigated in a tandem micro-pyrolyzer. The effects of temperature and particle size on the phenolic compounds and hemicellulose products distribution were examined during fast pyrolysis process. For this, changes in the micro-reactor parameters were made (particle ...
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Fast pyrolysis of sugarcane bagasse was investigated in a tandem micro-pyrolyzer. The effects of temperature and particle size on the phenolic compounds and hemicellulose products distribution were examined during fast pyrolysis process. For this, changes in the micro-reactor parameters were made (particle size between 0.1 and 0.5 mm and reactor temperature between 450 and 600 °C). Response Surface Methodology (RSM) was used to optimize pyrolysis parameters. The results indicated that the temperature had the highest effect on phenolic and furfural-type compounds, whereas the particle size did not exhibit significant effects on carboxylic acid products. The largest number of phenolic compounds were achieved upon decreasing the temperature and increasing particle size. The ANOVA analysis revealed that the full quadratic model was more adequate for phenolic and furfural compounds, whereas the linear square model was accurate for carboxylic acids. In general, a tandem micro-pyrolyzer interfacing with a GC-MS analysis facilitated a better understanding of a chemical composition of biomass and therefore, could remarkably improve the valorising of sugarcane bagasse application in biorefinery processes.
