Research Article
Advanced Energy Technologies
Sedigheh Sadegh Hassani; Leila Samiee
Abstract
In the present work, natural biomass and chemical materials were applied as the heteroatom resources for modifying the Porous Graphene (PG) structure by pyrolysis method at 900 ºC. The physical and chemical characterizatons were performed by means of Scanning Electron Microscopy (SEM), Brunauer–Emmett–Teller ...
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In the present work, natural biomass and chemical materials were applied as the heteroatom resources for modifying the Porous Graphene (PG) structure by pyrolysis method at 900 ºC. The physical and chemical characterizatons were performed by means of Scanning Electron Microscopy (SEM), Brunauer–Emmett–Teller (BET), Raman Spectroscopy, N2 Adsorption-Desorption, and X-ray Photo-electron Spectroscopy (XPS). Furthemore, the behavior of the prepared materials was investigated by Cyclic Voltammetry (CV) and Rotating Disk Electrode (RDE). The obtained results indicated that doping of heteroatoms into the graphene framework was possible using a low-cost and environment-friendly biomass material as well as chemical sources. Moreover, one-step quarternary and tersiary co-doped graphene could be acheived using natural biomass. The prepared electrocatalysts using grape leaves and sulfur trioxide pyridine complex exhibit higher electrocatalytic performance as exampled which conducted the electrocatalyst in 4e- pathway and showed high stability in methanol solutions during the process, confirming their considerable potential to Oxygen Reduction Reaction (ORR) as an electro-catalyst. Moreover, the onset potential of Gl300G-900 and GSP 900 (0.93 V vs RHE) is almost equal to the Pt/C 20 wt % (0.99 V vs RHE). These optimal prepared cathodes (Gl300G-900 and GSP 900) in the Microbial Fuel Cell (MFC) test lead to considerable power densities of 31.5 mW m-2 and 30.9.mW m-2, which are close to 38.6 mW m-2 for the Pt/C 20 wt % cathode.
Research Article
Environmental Impacts and Sustainability
Abotaleb Bay; Payam Ghorbannezhad; Javad Yazdan Moghadam; Rahim Aali
Abstract
The wastewater treatment of Medium Density Fiberboard (MDF) is a harsh process because of its contents of high suspended solids, chemical oxygen demand, high molecular weight of lignin, and fatty acids. Electrocoagulation (EC) process was used for efficient removal of pollutants and reusing the water. ...
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The wastewater treatment of Medium Density Fiberboard (MDF) is a harsh process because of its contents of high suspended solids, chemical oxygen demand, high molecular weight of lignin, and fatty acids. Electrocoagulation (EC) process was used for efficient removal of pollutants and reusing the water. The impact of aluminum and iron as sacrificial anodes on removal of Chemical Oxygen Demand (COD), Total Suspended Solid (TSS), turbidity, and Total Solid (TS) were investigated. A full quadratic model was deployed to optimize the EC process variables for pretreatment of MDF effluent through response surface methodology. The model results confirmed that the COD and TSS removal efficiency was enhanced upon increasing voltage and residence time; hence, other pollutants initially increased and then, decreased at higher levels. The comparison between aluminum and iron electrodes indicated that the polluted removal efficiencies of aluminum were higher than the iron electrode for MDF wastewater. The optimum values of voltage and residence time for electrocoagulation of MDF wastewater with aluminum were 33 V and 25 min, which resulted in 93 %, 89 %, 67 %, and 76 % for COD, TSS, turbidity, and TS removal, respectively. The implementation of electrocoagulation provided a possibility for reusing water and reducing water consumption in the MDF manufacturing process.
