Renewable Energy Resources and Technologies
Tazkieh Gilvari; Behzad Aghabarari; Mohammad Pazouki
Abstract
This study investigated the esterification reaction of different carboxylic acids (Acetic acid, Palmitic acid, and Oleic acid) and ethanol by ZnO, Al2O3-ZnOmixed oxide, and phosphotungestic acid (10 wt %) immobilized on the Al2O3-ZnOmixed oxide. The heterogeneous catalysts were characterized by XRD, ...
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This study investigated the esterification reaction of different carboxylic acids (Acetic acid, Palmitic acid, and Oleic acid) and ethanol by ZnO, Al2O3-ZnOmixed oxide, and phosphotungestic acid (10 wt %) immobilized on the Al2O3-ZnOmixed oxide. The heterogeneous catalysts were characterized by XRD, BET, FE-SEM, and EDX techniques. Optimum yield was achieved by using 10 % HPW/Al2O3-ZnOas the best catalyst, and the effects of the amount of catalyst, molar ratio of acid to alcohol, reaction temperature, and time were investigated to ensure the ideal yield of esterification reaction of acetic acid and ethanol. The results showed that the esterification of acetic acid to its ethyl ester was carried out in 3.5 hours, with an alcohol-to-acid-molar ratio of 2 and a temperature of 80 ˚C with yield 98 %. Moreover, the 10 % HPW/Al2O3-ZnOcatalystshowed well activity in biodiesel production by the esterification of palmitic and oleic acids and the reaction yield did not decrease with an increase in alkyl chain lengthin acid molecules, remarkably.
Renewable Energy Resources and Technologies
Bahman Heydari; Shahin Rafiee; Elham Abdollahzadeh Sharghi; Seyed Saeid Mohtasebi
Abstract
The aromatic and dark-colored spearmint essential oil wastewater (SEOW) generally contains a large amount of organic matter, including chemical oxygen demand (COD), phenolic compounds, and inorganic contents. In this study, the pollutant removal performance and biogas production rate of an up-flow anaerobic ...
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The aromatic and dark-colored spearmint essential oil wastewater (SEOW) generally contains a large amount of organic matter, including chemical oxygen demand (COD), phenolic compounds, and inorganic contents. In this study, the pollutant removal performance and biogas production rate of an up-flow anaerobic sludge blanket (UASB) reactor used for the treatment of SEOW were investigated. During the 102 days UASB operation at hydraulic retention time of 60 hours, the organic loading rate (OLR) was increased from 0.14 to 2.69 kg COD/m3.d by increasing the influent SEOW concentration. With increasing OLR from 0.14 to 2.69 kg COD/m3.d, the concentrations of COD and phenol in the influent of the UASB reactor increased to 6720±383 mg/L and 383±88 mg/L, respectively. At OLR equal to 2.69 kg COD/m3.d, the steady-state average removal efficiencies of COD and phenol were 72.0±1.4 and 63.1±6.7 %, respectively. The stability of the anaerobic system was confirmed by the average steady-state ratios of the volatile fatty acid/alkalinity and pH in the UASB reactor, which were less than 0.4 and 7.5±0.1, respectively, at different OLRs. The optimum OLR was found to be 2.69 kg COD/m3.d, where 26.9±1.7 L/d production of biogas containing 63.0±5.2 % and 22.4±4.2 % methane and carbon dioxide, respectively, was obtained. Moreover, at OLR equal to 2.69 kg COD/m3.d, the biogas yield and net heating value were 462.2±46.9 L/kg CODremoved and 24.7±5.2 MJ/m3, respectively. The results of the current study reveal the substantial potential of the UASB reactor in terms of pollutant removal performance and biogas production for the treatment of SEOW.
